Heartbreakers (2001)

Max (Sigourney Weaver) and Page (Jennifer Love Hewitt) are a brilliant mother/daughter con team who have their grift down to a fine science. Max targets wealthy, willing men who fall prey to her beauty and charm, and marries them. The equally gorgeous Page then seduces them. Max "catches" her wayward husbands in the act. Then it's off to alimony city - with the hapless men losing much more than their shirts - and on to the next mark, with Max and Page posing in a variety of deceptive guises to keep one (or two) steps ahead of the law.